Product ID:FYRQUEL 220 MLT
MSDS Date:10/23/1998
FSC:9150
NIIN:01-113-2047
MSDS Number: CFFGQ

Emergency Phone: 914-693-6946

Info Phone: 800-666-1200

Cage: 01GF0

Telephone: 800-666-1200

Cage: 01GF0

TRIPHENYL PHOSPHATE

CAS: 115-86-6

RTECS: TC8400000

OSHA PEL 3 MG/M3

ACGIH TLV: 3 MG/M3; 9596

BUTYLATED TRIPHENYL PHOSPHATE MIXTURE

LD50 LC50 Mixture:LD50(RAT) >5000MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE MILD SKIN/EYE IRRITATION.
INHALATION OF VAPOR/MIST MAY CAUSE RESPIRATORY TRACT IRRITATION.
TRIPHENYL PHOSPHATE MAY CAUSE CHOLINESTERASE INHIBITION AT LEVELS
ABOVE EXPOSURE LIMITS. INHALATION : VAPOR/MIST MAY CAUSE
RESPIRATORY TRACT IRRITATION. TRIPHENYL PHOSPHATE CAN CAUSE
CHOLINESTERASE INHIBITION. SKIN:CONTACT MAY CAUSE MILD IRRITATION.
EYE: CONTACT MAY CAUSE MILD IRRITATION. INGESTION: MAY CAUSE
IRRITATION OF GASTROINTESTINAL SYSTEM & DIARRHEA. INGESTION OF
TRIPHENYL PHOSPHATE, A COMPONENT, MAY CAUSE CHOLINESTERASE
INHIBITION. TARGET ORGANS: SKIN, EYES, RESPIRATORY SYSTEM, CENTRAL
NERVOUS SYSTEM.
Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY:
IARC/NTP/OSHA/ACGIH: NO.
Effects of Overexposure:EYE/SKIN: MAY CAUSE MILD IRRITATION. INGESTION:
MAY CAUSE IRRITATION OF GI SYSTEM & DIARRHEA. INGESTION OF
TRIPHENYL PHOSPHATE MAY CAUSE CHOLINESTERASE INHIBITION -HEADACHE,
NAUSEA, SWEATING, NUMBNESS , TINGLING OF HANDS/FEET, SALIVATION,
MUSCLE TWITCHING, TREMORS, INCOORDINATION, BLURRED VISION, TEARS,
ABDOMINAL CRAMPS, DIARRHEA, CHEST DISCOMFORT.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING
NEUROMUSCULAR DISORDERS MAY BE AT AN INCREASED RISK FROM EXPOSURE
TO MATERIAL.

First Aid:INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING GIVE CPR OR
OXYGEN IF BREATHING DIFFICULT. SKIN: REMOVE CONTAMINATED CLOTHES.
WASH ALL AFFECTED AREAS WITH SOAP & PLENTY WATER. GET MEDICAL HELP
IF IRRI TATION PERSISTS. WASH CONTAMINATED CLOTHES BEFORE REUSE.
CLEAN OR DESTROY CONTAMINATED SHOES. EYES: IMMEDIATELY FLUSH WITH
PLENTY RUNNING WATER. REMOVE CONTACTS. HOLD EYELIDS OPEN. GET
MEDICAL HELP. I NGESTION: CALL PHYSICIAN OR POISON CONTROL CENTER.
DO NOT INDUCE VOMITING UNLESS SO DIRECTED BY MEDICAL PERSONNEL. IF
VOMITING OCCURS, KEEP HEAD BELOW HIPS TO REDUCE RISK OF ASPERATION.
NEVER GIVE ANY THING BY MOUTH IF UNCONSCIOUS.

Flash Point Method:PMCC
Flash Point:=246.1C, 475.F
Autoignition Temp:Autoignition Temp Text:N/D
Lower Limits:N/D
Upper Limits:N/D
Extinguishing Media:WATER FOG OR SPRAY, DRY CHEMICAL, FOAM OR CARBON
DIOXIDE.
Fire Fighting Procedures:WEAR FULL-FACE, SELF-CONTAINED BREATHING GEAR
& IMPERVIOUS CLOTHING. KEEP FIRE EXPOSED CONTAINERS COOL WITH WATER
FOG OR SPRAY TO PREVENT RUPTURE. HIGH PRESSURE WATER MAY SPREAD
PRODUCT FROM BROKEN CO NTAINERS & INCREASE CONTAMINATION OR FIRE
HAZARD. DIKE FIRE CONTROL WATER FOR LATER DISPOSAL.
Unusual Fire/Explosion Hazard:PRODUCT NOT DEFINED AS
FLAMMABLE/COMBUSTIBLE. IS SELF-EXTINGUISHING ONCE IGNITION SOURCE
IS REMOVED. NOT SENSITIVE TO STATIC DISCHARGE OR PHYSICAL IMPACT.
MAY DECOMPOSE UNDER FIRE CONDITIONS TO CARBON MONOXIDE, PHOSPHORUS
OXIDES, ORGANIC DECOMPOSITION PRODUCTS.

Spill Release Procedures:ISOLATE SPILL & RESTRICT ACCESS. CLEAN UP
PERSONNEL SHOULD FOLLOW INDUSTRIAL HYGIENE PRACTICES. STOP SOURCE
OF SPILL & DIKE. SOAK UP WITH ABSORBENT LIKE CLAY, SAWDUST, KITTY
LITTER. SWEEP UP ABSORBED MATERIAL & PUT IN WASTE CONTAINER FOR
DISPOSAL. SPILL AREA MAY BE SLIPPERY. CLEAN WITH DETERGENT & WATER.
USE STIFF BRUSH TO CLEAN CRACKS. FLUSH WITH WATER BUT DO NOT ALLOW
WATER TO ENTER WATERWAYS.
Neutralizing Agent:NOT PROVIDED

Handling and Storage Precautions:STORE IN COOL DRY WELL VENTILATED AREA
AWAY FROM FLAMMABLES, OXIDIZERS, HEAT SOURCES. AVOID PROLONGED
STORAGE AT ELEVATED TEMPERATURES UNDER ALKALINE/ACIDIC CONDITIONS.
MAX STORAGE TEMP: 149F. CARBON STEEL IS PREFERRED STORAGE
CONTAINER. ROTATE CONTAINERS REGULARLY & INSPECT FOR DAMAGE.
Other Precautions:WEAR PROTECTIVE CLOTHING, CHEMICAL GOGGLES, RUBBER
GLOVES. AVOID SKIN/EYE CONTACT & INHALING VAPORS. EMPTY CONTAINERS
MAY CONTAIN RESIDUES. STORE AWAY FROM FOOD OR ANIMAL FEED. BELOW
40F VISCOSITY CHA RACTERISTICS MAY REQUIRE PRODUCT HEATING TO PUMP
IT. VENT BULGED DRUMS SLOWLY IN OPEN AREA.

Respiratory Protection:NIOSH-APPROVED ORGANIC/ACID GAS RESPIRATOR WITH
DUST, MIST & FUME FILTER. IF HIGHER PROTECTION IS NEEDED US
NIOSH-APPROVED POSITIVE-PRESSURE, PRESSURE DEMAND, AIR-SUPPLIED
RESPIRATOR. WHEN USING RESPI RATOR CARTRIDGES OR CANISTERS, THEY
MUST BE CHANGED FREQUENTLY (FOLLOWING USE OR END OF WORK SHIFT).
Ventilation:AT ELEVATED TEMPERATURS OR AIRBORNE VAPOR HANDLE IN WELL
VENTILATED AREA. OTHERWISE USE NIOSH-APPROVED POSITIVE-PRESSURE
AIR-SUPPLIED RESPIRATOR.
Protective Gloves:COMBINATION NEOPRENE OVER NATURAL LATES GLOVES
RECOMMENDED
Eye Protection:CHEMICAL SAFETY GOGGLES OR FACE SHIELD
Other Protective Equipment:SAFETY SHOWERS WITH QUICK OPENING VALVES,
EYE WASH FOUNTAINS. WATER SUPPLIED THROUGH INSULATED HEAT TRACED
LINES TO PREVENT FREEZING. LONG SLEEVED SHIRTS.
Work Hygienic Practices:WASH CONTAMINAED CLOTHING BEFORE REUSE;
THOROUGHLY CLEAN OR DESTROY CONTAMINATED SHOES.
Supplemental Safety and Health

HCC:V6
Boiling Pt:B.P. Text:N/D
Melt/Freeze Pt:M.P/F.P Text:N/D
Vapor Pres:<0.1
Vapor Density:N/D
Spec Gravity:N/D
pH:N/D
Viscosity:220SUS @38C
Evaporation Rate & Reference:N/D
Solubility in Water:<0.1G/100ML,NEGLIG
Appearance and Odor:CLEAR, BLUE LIQUID, ESSENTIALLY ODORLESS
Percent Volatiles by Volume:N/D
Corrosion Rate:N/D

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, STRONG ACIDS, STRONG ALKALIS. HYDROLYXES SLOWLY AT
AMBIENT TEMPERATURE IN ACIDIC/ALKALINE AQUEOUS SOLUTIONS.
Stability Condition to Avoid:PRODUCT STABLE AT AMBIENT TEMPERATURE &
ATMOSPHERIC PRESSURE. NOT SELF REACTIVE & NOT SENSITIVE TO STATIC
DISCHARGE.
Hazardous Decomposition Products:CARBON MONOXIDE, PHOSPHORUS OXIDES,
ORGANIC DECOMPOSITION PRODUCTS. HYDROLYZES TO FORM
PHENOL,SUBSTITUTED PHENOLS & ARYL PHOSPHORIC ACIDS.

Waste Disposal Methods:MATERIAL THAT CANNOT BE RECYCLED SHOULD BE
DISPOSED OF IAW ALL APPLICABLE REGULATIONS. SINGLE USE PRODUCT
CONTAINERS MUST BE THOROUGHLY CLEANED. STATE/LOCAL REGULATIONS MEY
BE MORE STRINGENT THAN FEDE RAL. UNUSED PRODUCT DOES NOT MEET RCRA
CRITERIA AS LISTED OR CHARACTERISTIC WASTE. GENERATORS MUST E
VALUATE WASTE STREAM. DRAIN CONTAINERS IAW REGS.

Toxicological Information:ACUTE INHALATION LC50 (RAT) FOR MATERIAL
FOLLOWING 4-HR EXPOSURE WAS > 3.1 MG/L, THE HIGHEST ATTAINABLE
CONCENTRATION. NO EFFECTS OBSERVED AT THIS LEVEL. CHRONIC
INHALATION EFFECTS ARE NOT KNOWN. DERM AL: PRACTICALLY NON-TOXIC,
ACUTE DERMAL LD50 (RABBIT) > 2000 MG/KG. MATERIAL FOUND TO BE MILD
SKIN IRRITANT IN RABBITS FOLLOWING 24 RH EXPOSURE. CONTACT DERMAL
EXPOSURE FOR PRODUCT NOT KNOWN. HOWEVER, PROLONGED/REPEATED
CONTACT MAY CAUSE IRRITATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:96 HR LC50 (RAINBOW TROUT): > 2 MG/L. TRIARYL PHOSPHATE
ESTERS, INCLUDING TRIPHENYL PHOSPHATE, EXHIBIT LOW AQUEOUS
SOLUBILITY, HAVE MODERATE POTENTIAL FOR BIOCONCENTRATION & READILY
UNDERGO PRIMARY & ULTIMATE BIODEGRATION BY NATURALLY OCCURING
MIXED-MICROBIAL POPULATIONS PRESENT IN ACTIVATED SLUDGE & RIVER
WATER. CHEMICAL FATE: PRODUCT IS READILY BIODEGRADABLE. HYDROLYSIS
RATE FOR TRIPHENYL PHOSPH ATE: PH = 9.5, HALF-LIFE 1.3 DAYS; PH =
8.2, HALF-LIFE 7.5 DAYS. AT NEUTRAL & ACIDIC PH: TO SLOW TO
RELIABLY MEASURE.

Transport Information:ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S (TRIPHENYL PHOSPHATE), CLASS 9, UN 3082, PG III, NORTH
AMERICAN EMERGENCY GUIDE NO. 171.

Federal Regulatory Information:TRIPHENYL PHOSPHATE LISTED ON TSCA.
State Regulatory Information:TRIPHENYL PHOSPHATE SUBJECT TO FOLLOWING:
DOMESTIC SUBSTANCE LIST-CANADA, MASSACHUSETTS SUBSTANCE LIST, NEW
JERSEY RTK LIST, PENNSYLVANIA HAZARDOUS SUBSTANCE LIST.